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A covalent bond results when __________


A) electrons are transferred from one atom to another atom.
B) atoms pool their electrons to form a "sea" of electrons.
C) atoms have outer electrons with the same principal quantum number.
D) electrons are shared between a pair of atoms.
E) an atom has 8 valence electrons.

F) B) and E)
G) A) and B)

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Which of the following compounds would have the largest enthalpy of formation? The bond energies are given in parentheses.


A) H Br (366 kJ/mol)
B) H I (299 kJ/mol)
C) H Cl (431 kJ/mol)
D) H F (567 kJ/mol)
E) H H (436 kJ/mol)

F) D) and E)
G) C) and D)

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The formal charge on the oxygen atoms in the Lewis structure for sulfur dioxide (SO2) that minimizes the formal charges is __________


A) 0 for both oxygen atoms.
B) +1 for both oxygen atoms.
C) -1 for both oxygen atoms.
D) 0 for one oxygen atom, -1 for the other.
E) +1 for one oxygen atom, -1 for the other.

F) A) and B)
G) A) and C)

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Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide?


A) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)
B) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)
C) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)
D) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)

E) All of the above
F) A) and B)

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Indicate which molecule contains the largest number of nonbonding electrons.


A) H2
B) CO
C) N2
D) NO
E) O2

F) None of the above
G) C) and D)

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Indicate which of the following molecules has four shared electrons.


A) O2
B) CO
C) HI
D) N2
E) Cl2

F) B) and D)
G) A) and D)

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Do you expect the nitrogen-oxygen bond length in the nitrate anion (NO3-) to be the same as in the nitrite anion (NO2-)? Explain why or why not.

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In examining the Lewis structures to ide...

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Which of the following ions does not have a complete valence-shell octet?


A) B3+
B) I-
C) Ca2+
D) Pb2+
E) S2-

F) A) and B)
G) D) and E)

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Indicate the element with the smallest electronegativity.


A) Cl
B) F
C) Be
D) K
E) C

F) All of the above
G) C) and D)

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What is the formal charge of the nitrogen atom in hydrogen cyanide (HCN) ?


A) -1
B) 0
C) 1
D) 5
E) 2

F) None of the above
G) A) and D)

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In general, resonance __________ electrons and __________ molecules.


A) delocalizes, stabilizes
B) destabilizes, destabilizes
C) localizes, stabilizes
D) delocalizes, destabilizes
E) Localizes, stabilizes

F) A) and E)
G) B) and C)

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Which molecule has a stretching vibration that is not infrared active?


A) CO2
B) OCS
C) H2O
D) NH3
E) HCl

F) B) and C)
G) A) and E)

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Based on the positions of the atoms in the periodic table, arrange the following bonds in order of increasing bond length: C O, S O, C C.

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C F1F...

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Identify which of the following molecules has a bond order of 3: Li2, Be2, N2, F2, C2.

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Which group of elements is listed in order of increasing electronegativity?


A) F < Cl < Ge < Sn
B) Rb < Ca < Sc < Cs
C) Zr < V < Nb < Ta
D) In < Ga < Al < C
E) Cl < Br < I < F

F) B) and E)
G) None of the above

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Which one of the following molecules or ions contains an exception to the octet rule?


A) O2
B) CN-
C) XeCl
D) ClO-
E) SiH4

F) B) and E)
G) A) and B)

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In which of the following molecules does the central atom have an expanded octet?


A) N2O
B) PCl5
C) BeF2
D) AsF3
E) NO2

F) B) and E)
G) A) and B)

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Identify the molecule below that contains a double bond.


A) HCN
B) O3
C) C2H2
D) S2
E) N2

F) None of the above
G) D) and E)

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When sulfur-containing fuels are burned, sulfur trioxide (SO3) is formed in the atmosphere and contributes to acid rain (sulfur trioxide plus water produces sulfuric acid) . How many resonance structures are there for SO3 when each atom satisfies the octet rule?


A) 0
B) 1
C) 2
D) 3
E) 4

F) B) and E)
G) A) and B)

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What is the total number of electrons assigned to the oxygen atom in the Lewis structure of formaldehyde (H2CO) ?


A) 8
B) 6
C) 4
D) 2
E) 10

F) B) and C)
G) B) and E)

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