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What is the total number of electrons assigned to the oxygen atom in the Lewis structure of formaldehyde (CH2O) ?


A) 8
B) 6
C) 4
D) 2
E) 10

F) C) and E)
G) C) and D)

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Which one of the following molecules violates the octet rule?


A) SF4
B) COF2
C) PBr3
D) S2Cl2
E) SiH4

F) D) and E)
G) B) and E)

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Which of the following bonds is considered to be ionic: C__O, Ca__l, S__N, and Si__O. Explain why.

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Ca__Cl is considered...

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In comparing the length and strength of single, double, and triple bonds between the same pair of atoms, the ______


A) shorter bond will be the stronger bond.
B) shorter bond will be the weaker bond.
C) longer bond can be either weaker or stronger than the other.
D) bond length and bond strength are not related.
E) longer bond will be the stronger bond.

F) All of the above
G) A) and D)

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The formal charge on the sulfur atom in the Lewis structure for sulfur dioxide (SO2) that minimizes the formal charges is ________


A) 0.
B) +1.
C) -1.
D) +2.
E) -2.

F) None of the above
G) B) and D)

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Indicate which molecule contains the largest number of nonbonding electrons.


A) H2
B) CO
C) N2
D) NO
E) O2

F) All of the above
G) A) and B)

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Which one of the molecules below has 10 electrons around the central atom in a Lewis structure that has all atoms with a formal charge of zero? I. POCl3 II. PF3 III. SO3 IV. SOF2


A) I only
B) II only
C) III only
D) IV only
E) both I and IV

F) A) and E)
G) D) and E)

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Which of the following compounds is likely to have the least reactive hydrogen?


A) H--Br (141 pm)
B) H--I (161 pm)
C) H--Cl (127 pm)
D) H--F (92 pm)
E) H2S (134m)

F) D) and E)
G) A) and E)

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Electronegativity increases from left to right across a period because of ________


A) increased shielding of valence electrons by the core electrons.
B) an increase in the number of protons in the nucleus.
C) a decrease in the effective nuclear charge (Zeff) .
D) an increase in the shielding of core electrons by the valence electrons.
E) a decrease in the ionization potential.

F) A) and B)
G) A) and E)

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Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide?


A) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)
B) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)
C) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)
D) Carbon dioxide is a greenhouse gas. Which of the following is the correct Lewis structure for carbon dioxide? A)    B)    C)    D)

E) None of the above
F) C) and D)

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Nitrite (NO2-) is an important nutrient in the eutrophic zone of the ocean. Which of the following is the correct set of resonance structures for this ion? Nitrite (NO<sub>2</sub><sup>-</sup>)  is an important nutrient in the eutrophic zone of the ocean. Which of the following is the correct set of resonance structures for this ion?   A)  I B)  II C)  III D)  IV


A) I
B) II
C) III
D) IV

E) A) and D)
F) All of the above

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Draw the Lewis structure for the nitrate anion, NO3-. Include resonance structures if necessary.

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blured image Two other structures should b...

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Identify the molecule below that contains a double bond.


A) HCN
B) O3
C) C2H2
D) S2
E) N2

F) A) and B)
G) A) and C)

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Which of the following bonds is the weakest?


A) C--O
B) C=O
C) O=O
D) O?O

E) B) and C)
F) A) and D)

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Which of the following is the longest bond? The number in parentheses is the bond energy.


A) C-C (348 kJ/mol)
B) C-F (453 kJ/mol)
C) C-H (411 kJ/mol)
D) C-Cl (339 kJ/mol)
E) C-O (358 kJ/mol)

F) B) and C)
G) A) and E)

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Rank the following species in order of increasing nitrogen-oxygen bond energy: NO+, NO2-, NO3-.

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In order from larges...

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Which group of elements is listed in order of increasing electronegativity?


A) F < Cl < Ge < Sn
B) Rb < Ca < Sc < Cs
C) Zr < V < Nb < Ta
D) Sn < P < Cl < F
E) Cl < Br < I < F

F) None of the above
G) C) and E)

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How many valence electrons does aluminum have?


A) 1
B) 2
C) 3
D) 11
E) 13

F) A) and B)
G) All of the above

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Based on the positions of the atoms in the periodic table, arrange the following bonds in order of increasing bond length: H__H, H__Br, H__Cl.

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Hydrogen cyanide (HCN) and hydrogen isocyanide (HNC) have the same elemental composition except H is bonded to carbon in one and to nitrogen in the other. Which statement regarding the Lewis structures of these molecules is not correct?


A) Both have 10 valence electrons.
B) The formal charges are zero for all the atoms in only one of these molecules.
C) The most electronegative element has a formal charge of -1 in one of these molecules.
D) The Lewis structures predict that HCN is the more stable molecule.
E) The formal charges sum to zero in both molecules.

F) C) and D)
G) None of the above

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